Add the ingredients to a small bowl and combine. Rub into both sides of the pork chops. Cover and refrigerate for 1-2 hours.
Remove from the refrigerator and let come to room temp for 40 minutes. During this time make the Maple Brandy Pears. Set aside to keep warm.
Heat the grill to 400 degrees F. Grease the grates and drizzle a small amount of high heat oil to the pork chops. Add the chops to the grill. Leave the cover off. Set a times for 4 minutes, but at 3 minute mark, or when the pork chop will release, turn about 90 degrees to get your crosshatch marks.
At 4 minutes, turn the pork chops over, moving them on the grill for even cooking. Set a timer for 4 minutes (3 minutes if they are thinner or boneless pork chops). At 2-3 minutes remaining on the timer, turn 90 degrees for grill marks.
When the second side timer goes off, begin checking the a few of the pork chops with a meat thermometer. When the pork is 3-5 degrees from your desired doneness (between 145-160), remove to a clean plate, using clean tongs or spatula.
Cover with foil and let rest for 5-10 minutes before serving. Serve with a few Maple Brandy Pears on top of each pork chop and pass the remaining pears to add more.